You probably have to rip each video separately.Use vobEdit to split the vob's to cells-i think you will find black only vob files separating each chapter,this is what is causing the out of sync issue.I ran into this on A Hard Days Night Disc 2 where a lot of small 3-5 min segments were combined into a few 0.99gb vob's.I thought i could demux the whole string of segments into one big m2v but i ran in to the sync issue so i had to split by cell and demux and it works fine(lots of work though).